"Over the past 20 years aqueous organometallic catalysis has found applications in small- scale organic synthesis in the laboratory, as well as in the industrial production of chemicals with a combined output close to one million tons per year. Aqueous/organic two-phase reactions allow easy product-catalyst separation and full catalyst recovery which mean clear benefits not only in economic but also in e ..."
"Catal. A. 1996, 111, 239 S. V. J. Mol. Catal. A. 1996, 110, 189 S. V. J. Mol. Catal.
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"Homogeneous hydrogenation is one of the most thoroughly studied fields of homogeneous catalysis. The results of these studies have proved to be most important for an understanding of the underlying principles of the activation of small molecules by transition metal complexes. During the past three decades homogeneous hydrogenation has found widespread application in organic chemistry, including the prod ..."
"In the last 15 years aqueous organometallic chemistry and catalysis has emerged from being a laboratory curiosity to become an established field of research. Topics reviewed here include mechanistic studies on the effect of water on catalyzed reactions, the preparation of water soluble phosphines as ligands for catalysis, metal catalyzed organic reactions in water (hydrogenation, hydroformylation, carbo ..."
"Instead of putting together a series of expert reviews of specialized fields, this book attempts to give a comprehensive yet comprehensible description of the various catalytic transformations in aqueous systems as seen by an author who has ..."
"Though the mechanism of some important reactions was investigated in detail [
60] in general there is still a lack of fundamental mechanistic studies of aqueous
organometallic reactions. A special question is that of the solubility of reactants (
e.g. gases) which may result in changes of mechanism. It is most important
therefore to establish the region where the reaction actually takes place (one or
both of the bulk phases or the in ..."
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